34860

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34860

Sigma-Aldrich

 

Methanol

CHROMASOLV®, for HPLC, ≥99.9%

Synonym:Methyl alcohol
CAS Number:67-56-1
Linear Formula:CH3OH
Molecular Weight:32.04
Beilstein Registry Number:1098229
EC Number:200-659-6
MDL number:MFCD00004595
PubChem Substance ID:24861591

Description

Frequently Asked QuestionsLive Chat and Frequently Asked Questions are available for this Product.
Packaging100 mL in glass btl
 200, 400 L in Pure-Pac™ 1
 7, 18, 45 L in ss drum
 100 mL, 1 L, 12×100 mL, 2 L, 4 L, 6×1 L, 4×2 L, 4×4 L packaged in glass bottles; 56 L, 200 L, 400 L packaged in Pure-Pac® stainless steel containers. Pure-Pac II containers require the Micromatic MacroValve coupler, Z560723, for dispensing solvent.
 1, 6×1, 144×1, 2, 4×2, 2.5, 4×2.5, 72×2.5, 4, 4×4 L in glass btl
Legal InformationCHROMASOLV is a registered trademark of Sigma-Aldrich Biotechnology LP and Sigma-Aldrich Co.
 Pure-Pac is a registered trademark of Sigma-Aldrich Biotechnology LP and Sigma-Aldrich Co.

Properties

gradeCHROMASOLV®
 for HPLC
vapor density1.11 (vs air)
vapor pressure410 mmHg ( 50 °C)
 97.68 mmHg ( 20 °C)
assay≥99.9%
autoignition temp.725 °F
expl. lim.36 %
total impurities≤0.0005% non-volatile matter
 ≤1 ppb fluorescence (quinine) at 254 nm
 ≤1 ppb fluorescence (quinine) at 365 nm
 <0.03% water (Karl Fischer)
evapn. residue <0.0005%
refractive indexn20/D 1.329(lit.)
bp64.7 °C(lit.)
mp−98 °C(lit.)
density0.791 g/mL at 25 °C(lit.)
λ neat
UV absorptionλ: 210 nm Amax: 0.50
 λ: 220 nm Amax: 0.30
 λ: 235 nm Amax: 0.10
 λ: 260 nm Amax: 0.01

Safety

Personal Protective EquipmentEyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
Hazard CodesF,T
Risk Statements11-23/24/25-39/23/24/25
Safety Statements7-16-36/37-45
RIDADRUN1230 3/PG 2
WGK Germany1
RTECSPC1400000
UEL36.00%(V)
LEL6.00%(V)
Flash Point(F)51.8 °F
Flash Point(C)11 °C

Related Products

Required but not providedZ560723, Micromatic MacroValve coupler for returnable containers - Pure-Pac® II containers require the Micromatic Macrovalve for dispensing solvents.
Related productZ568074, Pure Solv Micro replacement purification column
 Z568031, Pure Solv Micro 100 Liter solvent purification system

References

MerckMerck 13,5984
BeilsteinBeil. 1,IV,1227
referenceAldrich MSDS 1, 1202:C / Corp MSDS 1 (2), 2281:C / FT-IR 2 (1), 160:B / FT-IR 1 (1), 109:B / FT-NMR 1 (1), 163:A / IR-Spectra (3), 66:A / IR-Spectra (2), 64:A / NMR-Reference 2 (1), 101:A / RegBook 1 (1), 121:A / Sax 6, 1764 / Sigma FT-IR 1 (1), 1344:A / Structure Index 1, 14:A:1 / Vapor Phase 3, 155:B